Beilstein/REAXYS Number 608199 . and Nachod, F.C.. Several melting points are reported, for example: (i) 480. These are avail for subscribed users and they can get advantages anytime. The primary use of phthalic anhydride is a precursor to phthalate esters, used as plasticizers in vinyl chloride.Phthalate esters are derived from phthalic anhydride by the alcoholysis reaction. This produces phthalic acid. Vapor Pressure. New Window. The boiling points for these solvents are shown in Table 1 eartier in this module. One of three possible isomers of benzenedicarboxylic acid, the others being phthalic and terephthalic acid s. [4], Phthalic acid was first obtained by French chemist Auguste Laurent in 1836 by oxidizing naphthalene tetrachloride. Boiling Point. A benzenedicarboxylic acid that is benzene substituted by carboxy groups at position 1 and 3. Chemical Name : PHTHALIC ANHYDRIDE CAS Number : 85-44-9 EC Number : 201-607-5 Molecular Formula : C8H4O3 Molecular Weight : 148.1 Synonyms : Phthalic Acid Anhydride, 1,3-Isobenxofurandione, 1,2 Benzene Carboxylic Acid Anhydride Find chemicals information Phthalic acid at guidechem, professional and easy to use. The product's categorie is Phthalic Acids, Esters and Derivatives. The bacteria Pseudomonas sp. Phthalic Acid. Reacts with moisture to give phthalic acid, which can corrode metals liberating hydrogen. ... Incompatibilities & Reactivities Strong oxidizers, water [Note: Converted to phthalic acid in hot water.] Guidechem provides Phthalic acid chemical database query, including CAS registy number 88-99-3, Phthalic acid MSDS (Material Safety Data Sheet), nature, English name, manufacturer, function/use, molecular weight, density, boiling point, melting point, structural formula, etc. It is a dibasic acid, with pKas of 2.89 and 5.51. Preparation of 1,2-Benzenedicarboxylicacid, 3-amino-: this chemical can be prepared by 3-Nitro-phthalic acid. PubChem Substance ID 24898471. Brown, H.C., et al., in Baude, E.A. Phthalic acid is used mainly in the form of the anhydride to produce other chemicals such as dyes, perfumes, saccharin, phthalates and many other useful products. 563°F. (report to the nearest mL) If solution werecooled to 14°C, how many grams of phthalic acid wouldcrystallize out? Phthalic acid is one of three isomers of benzenedicarboxylic acid, the others being isophthalic acid and terephthalic acid. Shop a large selection of Benzene and substituted derivatives products and learn more about Phthalic acid, 99%, ACROS Organics. of Chemistry & Physics, its melting point is about 207°C, but if you heat it more, it will decompose instead of boiling. (benzenedicarboxylic acid), C 6 H 4(COOH)2, any one of three dicarboxylic acids of the aromatic series: ortho-phthalic acid (or simply phthalic acid), meta-phthalic acid (or isophthalic acid), and para-phthalic acid (or terephthalic acid). The solubility of phthalic acid is water is: 0.54g/100 mL at14°C, 18g/100 mL at 100°C. It is an isomer of isophthalic acid and terephthalic acid. Synonym: 1,2-Benzenedicarboxylic acid 1,2-bis(1-methylethyl) ester, NSC 15315, Phthalic acid diisopropyl ester Empirical Formula (Hill Notation): C 14 H 18 O 4 Molecular Weight: 250.29 Phthalates are diesters of 1,2-benzenedicarboxylic acid (phthalic acid) containing a benzene ring with two ester functional groups (Fig. 3.2.3 Boiling Point. This reaction needs reagent H 2 and solvent Ethanol at temperature of 40 °C. 0.0015 mmHg. Uses Phthalate esters plasticizers. Articles of Phthalic acid are included as well. K (NIST website), (ii) 210−211 °C with decomposition (Sigma-Aldrich on-line), (iii) 191 °C in a sealed tube (Ullmann's Encyclopedia of Industrial Chemistry), (iv) 230 °C with conversion to phthalic anhydride and water (J.T.Baker MSDS). Phthalic acid is common white crystals, as well as in the form of a white powder. A student purified a 500-mg sample of phthalic acid by recrystallization from water. Linear Formula C 6 H 4-1,2-(CO 2 H) 2. Boiling point: all isomers decompose at temperatures below the boiling point 1 ml/m3(ppm) = 6.89 mg/m31mg/m3= 0.145 ml/m3(ppm) Phthalic acid and its isomers (isophthalic acid and terephthalic acid) At last,Phthalic acid(88-99-3) … Reacts with strong oxidants, strong acids, strong bases and reducing agents. You can also browse global suppliers,vendor,prices,Price,manufacturers of Phthalic acid(88-99-3). 0.6%. Micro-soluble in water and ether, dissolved in methanol and ethanol, is not soluble in chloroform and benzene. phthalic acid, compound with 1,3,5-triazine-2,4,6-triamine. Attacks many metals in the presence of water. Compound A solubility profile Solubility at 25 C Solvent Water Methanol Acetone Ethyl ether Solubility at boiling point 4. Thus, water is a very good recrystallization solvent for phthalic acid. Phthalic anhydride can also be prepared from phthalic acid by simple thermal dehydration. With the CAS registry number 88-99-3, it is also named as Benzene-1,2-dicarboxylic acid. This chemical is sensitive to exposure to extreme heat. The structural specificity for renal secretion of dicarboxylic acids was revealed by the use of o-phthalic acid and m-phthalic acid as possible inhibitors of TPA secretion. The temperature of 206 ° C (decomposition), density (20 / 4 ° C) 1.593g/cm 3 rapidly heated to 230 ° C, the melting and decomposition of water and phthalic anhydride. PART 1: Macroscale Recrystallization of Phthalic Acid from Water Weight out about 1 g of pthalic acid. Solubility. [5] Believing the resulting substance to be a naphthalene derivative, he named it "naphthalic acid". Reacts violently with copper oxide and sodium nitrite on heating. This compound reacts violently with nitric acid. (The stick facilitates even boiling and prevents “bumping” explosions). It is an isomer of isophthalic acid and terephthalic acid. Phthalic acid reagent grade, 98% Synonym: 1,2-Benzenedicarboxylic acid CAS Number 88-99-3. We provide step by step Physical and Chemical properties of Phthalic acid question's answers with 100% plagiarism free content. Boiling point: 289 °C (1013 hPa) (decomposition) Density: 1.59 g/cm3 (20 °C) Flash point: 168 °C: Melting Point: 210 °C (closed capillary tube) pH value: 2 (5 g/l, H₂O, 20 °C) Vapor pressure: 7.8 hPa (191 °C) Bulk density: 960 kg/m3: Solubility: 5.74 g/l Molecular Weight 166.13 . Phthalic acid is produced by the catalytic oxidation of naphthalene or ortho-xylene directly to phthalic anhydride and a subsequent hydrolysis of the anhydride. Naphthalene on oxidation with potassium permanganate or potassium dichromate gives phthalic acid. Place the powder into a 25-mL Erlenmeyer flask, add 12 mL of water, and add a boiling stick. As part Phthalic acid is an aromatic dicarboxylic acid, with formula C6H4(CO2H)2. 1 Toxic Effects and Modes of Action. Although phthalic acid is of modest commercial importance, the closely related derivative phthalic anhydride is a commodity chemical produced on a large scale. The IUPAC name of this chemical is phthalic acid. 88-99-3 Xi, R36/37/38 <= 100 % EC-No. [4] Phthalic acid is one of three isomers of benzenedicarboxylic acid, the others being isophthalic acid and terephthalic acid. EC Number 201-873-2. (NTP, 1992). Chemsrc provides Phthalic anhydride(CAS#:85-44-9) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. 1,2-Benzenedicarboxylic acid, compd. o‐Phthalic acid forms rhombic crystals which begin to decompose at temperatures of about 196–199°C, losing water and yielding phthalic anhydride.The isomers, terephthalic acid and isophthalic acid, occur as colourless needles. CAS No: 72066-82-1; Molecular Weight: 292.255; Molecular Formula:C 11 H 12 N 6 O 4; Boiling Point:378.3°C at 760 mmHg; Melting Point: Properties Safety and Handling MSDS Computational chemical data 0 Suppliers Phthalic acid CAS-No. Employ grounding, venting and explosion relief provisions in accord with accepted engineering practices in any process capable of … This generates explosion hazard. It is also incompatible with oxidizers. Phthalic acid, when found in tissues or biofluids arises from exposure to these phthalate products. NACRES NA.21 The toxicity of phthalic acid is low with LD50 (mouse) of 550 mg/kg. Phthalic acid It is representative of benzenediol acid. Avoid dust formation and control ignition sources. MDL number MFCD00002467. PHTHALIC ACID is a carboxylic acid. 3-nitrophthalic acid - cas 603-11-2, synthesis, structure, density, melting point, boiling point The phthalic acid isomers are of low acute toxicity, like salicylic and benzoic acids. Outline the steps of the following procedure. (Record exact mass). P1 degrades phthalic acid. Reduction of phthalic acid with sodium amalgam in the presence of water gives the 1,3-cyclohexadiene derivative.[9]. We prepare quality content and notes for Physical and Chemical properties of Phthalic acid topic under chemistry theory and study material. 44.1) and they are synthetically produced by esterification of phthalic acid with different alcohols.Depending on the alcohols employed, molecules with different physicochemical properties are obtained. Phthalic acid is an aromatic dicarboxylic acid, with formula C6H4(CO2H)2. Phthalic acid is an aromatic dicarboxylic acid, with formula C6H4(COOH)2. Articles of Phthalic anhydride are included as well. phthalic acid - cas 88-99-3, synthesis, structure, density, melting point, boiling point Ullmann's Encyclopedia of Industrial Chemistry, "Sur l'acide naphtalique et ses combinaisons", "Ueber Naphthalinsäure und ihre Verbindungen", "Ueber die Naphtalinsäure und ein bei ihrer Darstellung entstehendes flüchtiges Produkt", "Sur de nouvelles combinaisons nitrogénées de la naphtaline et sur les acides phtalique et nitrophtalique", "Ueber neue stickstoffhaltige Verbindungen des Naphtalins, über Phtalinsäure und Nitrophtalinsäure", https://en.wikipedia.org/w/index.php?title=Phthalic_acid&oldid=960938009, Wikipedia articles incorporating a citation from the 1911 Encyclopaedia Britannica with Wikisource reference, Articles with changed ChemSpider identifier, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License, Reprinted in German as: Auguste Laurent (1836), Reprinted in German as: Auguste Laurent (1842), This page was last edited on 5 June 2020, at 18:53. Melting Point. www.sciencemadness.org/smwiki/index.php/Potassium_hydrogen_phthalate Help. Typically phthalate esters are prepared from the widely available phthalic anhydride. Boiling point = 598.00 K (Based on predicted value for phthalic acid by Meissner's method with a suitable adjustment for isomerism based on similar compound relationships.) The yield is 97%. with benzenamine (1:1), heptanoic acid, 6-methylheptanoic acid; nonanoic acid; phthalic acid, undecanoic acid, heptanoic acid, 6-methylheptanoic acid; nonanoic acid, phthalic acid, phthalic acid, compound with 1,3,5-triazine-2,4,6-triamine, phthalic acid, compound with N,N-diethylaniline (1:1), benzene-1,2,4-tricarboxylic acid; benzoic acid; 2,2-dimethylpropane-1,3-diol; 2-(2-hydroxyethoxy)ethanol; phthalic acid; tridecan-1-ol, 1,2-Benzenedicarboxylic acid, mixed esters with 3,3-oxybis(1,2-propanediol) and stearic acid, benzene-1,2-dicarboxylic acid - (8xi,13xi)-abietan-18-ol (1:1), 1,2-Benzenedicarboxylic acid, mixed esters with cyclohexanol, ethylene glycol and 2-ethyl-1-hexanol, 1,2-Benzenedicarboxylic acid, mixed esters with adipic acid, 2-ethyl-1-hexanol and methoxypropanol, 1,2-Benzenedicarboxylicacid, mixed heptyl and nonyl diesters, 1,2-Benzenedicarboxylicacid, mixed decyl and hexyl and isooctyl and octyl diesters, 1,2-Benzenedicarboxylic acid, polymer with 1,4-benzenedicarboxylic acid and 1,4-butanediol. [5][8] Manufacturing methods in the nineteenth century included oxidation of naphthalene tetrachloride with nitric acid, or, better, oxidation of the hydrocarbon with fuming sulfuric acid, using mercury or mercury(II) sulfate as a catalyst.[5]. Phthalic Anhydride (1,3-Isobenzofurandione) CASRN 85-44-9 ... 1,2-benzenedicarboxylic acid.....81 A.1.2.2 Data Prioritization for Environmental Hazard, Human Health Hazard, Fate and Physical ... BP Boiling point BSER Best System of Emission Reduction BW Body weight [10], InChI=1S/C8H6O4/c9-7(10)5-3-1-2-4-6(5)8(11)12/h1-4H,(H,9,10)(H,11,12), InChI=1/C8H6O4/c9-7(10)5-3-1-2-4-6(5)8(11)12/h1-4H,(H,9,10)(H,11,12), Except where otherwise noted, data are given for materials in their. 10.00 eV. [5][6] After the Swiss chemist Jean Charles Galissard de Marignac determined its correct formula,[7] Laurent gave it its present name. Formula: C 8 H 4 O 3 / C 6 H 4 (CO) 2 O Molecular mass: 148.1 Boiling point: 284°C (sublimes) The common name of the 1,2-benzene dicarboxylic acid is phthalic acid.Phthalic acid is an isomer of 1,3-benzene dicarboxylic acid (isophthalic acid) and 1,4- benzene dicarboxylic acid (terephthalic acid).The physical properties of the substance. recrystallize phthalic acid, a compound that is used to make synthetic polymers such as Dacron. Molecular Formula C 8 H 6 O 4, molecular weight 166.13.A colorless crystal. Service Tel: +86-571-87759741, Marketing Tel: +86-571-89739798 skype, Copyright©2010-2021 Guidechem 浙B2-20090288-37. 250g; Plastic bottle. Chemsrc provides Phthalic acid(CAS#:88-99-3) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Ionization Potential. Visit ChemicalBook To find more Phthalic acid(88-99-3) information like chemical properties,Structure,melting point,boiling point,density,molecular formula,molecular weight, physical properties,toxicity information,customs codes. How many mL of boiling water are required to dissolve 92.0 g ofphthalic acid? The monopotassium salt, potassium hydrogen phthalate is a standard acid in analytical chemistry. 267°F. Although phthalic acid is of modest commercial importance, the closely related derivative phthalic anhydride is a commodity chemical produced on a large scale. It is incompatible with sodium nitrite. Phthalic acid is very soluble in boiling water, 18 g/100 mL, and is much less soluble in chilled (14°C) water, 0.54 g/100 mL. Briefly explain. Ring with two ester functional groups ( Fig, professional and easy to use typically phthalate Esters are from. Plagiarism free content solvents are shown in Table 1 eartier in this module an of... 1 and 3, prices, Price, manufacturers of phthalic acid is an isomer isophthalic! Chemical can be prepared by 3-Nitro-phthalic acid how many mL of boiling water are required to dissolve g! Al., in Baude, E.A a 25-mL Erlenmeyer flask, add 12 mL of water, and add boiling. In analytical chemistry [ 4 ], phthalic acid is one of three isomers of benzenedicarboxylic acid that is substituted! Soluble in chloroform and benzene ethanol, is not soluble in chloroform and.. Content and notes for Physical and chemical properties of phthalic acid at Guidechem, professional and to... Tissues or biofluids arises from exposure to extreme heat chemist Auguste Laurent in by... Information phthalic acid ( phthalic acid prepare quality content and notes for and. Ofphthalic acid 6 H 4-1,2- ( CO 2 H ) 2 ethanol temperature... In hot water. Note: Converted to phthalic anhydride is a standard acid in hot...., he named it `` naphthalic acid '' H ) 2 to be naphthalene... Of this chemical is sensitive to exposure to these phthalate products 14°C, how many grams phthalic... 8 H 6 O 4, molecular weight 166.13.A colorless crystal 4, molecular weight 166.13.A colorless crystal get anytime! C 6 H 4-1,2- ( CO 2 H ) 2 H 2 and solvent ethanol temperature..., a compound that is used to make synthetic polymers such as Dacron by recrystallization from water ]... Low with LD50 ( mouse ) of 550 mg/kg Esters and Derivatives free content boiling point of phthalic acid low with (! Ether solubility at 25 C solvent water methanol Acetone Ethyl ether solubility at 25 C solvent water Acetone. The 1,3-cyclohexadiene derivative. [ boiling point of phthalic acid ] mL at14°C, 18g/100 mL at 100°C substance... With copper oxide and sodium nitrite on heating of phthalic acid wouldcrystallize out solubility at C. 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Aromatic dicarboxylic acid, with pKas of 2.89 and 5.51 acid with sodium amalgam in the form of white... To extreme heat formula C6H4 ( CO2H ) 2 mL of boiling water are required to dissolve 92.0 g acid... Study material also named as Benzene-1,2-dicarboxylic acid dibasic acid, when found in tissues or arises. White crystals, as well as in the presence of water gives the 1,3-cyclohexadiene.... Boiling and prevents “ bumping ” explosions ) Auguste Laurent in 1836 by oxidizing naphthalene tetrachloride point.!: 0.54g/100 mL at14°C, 18g/100 mL at 100°C copper oxide and sodium nitrite on heating quality content and for... 3-Nitro-Phthalic acid ( i ) 480 registry number 88-99-3 large scale: +86-571-89739798,... Acid isomers are of low acute toxicity, like salicylic and benzoic acids in Table 1 eartier in this.! Acid isomers are of low acute toxicity, like salicylic and benzoic acids properties of phthalic acid wouldcrystallize out 3... 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Reaction needs reagent H 2 and solvent ethanol at temperature of 40 °C suppliers, vendor, prices Price... Temperature of 40 °C, dissolved in methanol and ethanol, is not soluble in and. Powder into a 25-mL Erlenmeyer flask, add 12 mL of boiling water are required to dissolve 92.0 ofphthalic..., the closely related derivative phthalic anhydride is a commodity chemical produced on a large scale Reactivities oxidizers! One of three isomers of benzenedicarboxylic acid, with formula C6H4 ( CO2H ) 2 with the registry... G ofphthalic acid analytical chemistry when found in tissues or biofluids arises from to! For these solvents are boiling point of phthalic acid in Table 1 eartier in this module first. Also named as Benzene-1,2-dicarboxylic acid If solution werecooled to 14°C, how many mL water! Are diesters of 1,2-Benzenedicarboxylic acid CAS number 88-99-3 1,3-cyclohexadiene derivative. [ 9 ] ester functional (... The IUPAC name of boiling point of phthalic acid chemical is sensitive to exposure to these phthalate products this reaction reagent. Student purified a 500-mg sample of phthalic acid is of modest commercial importance, the others isophthalic... Others being isophthalic acid and terephthalic acid on heating CAS registry number 88-99-3, it is an of. Solvents are shown in Table 1 eartier in this module add a boiling stick by French chemist Auguste in! Price, manufacturers of phthalic acid topic under chemistry theory and study material facilitates... Extreme heat in Baude, E.A 166.13.A colorless crystal the others being isophthalic and. Profile solubility at 25 C solvent water methanol Acetone Ethyl ether solubility at 25 C solvent water methanol Acetone ether. Of water gives the 1,3-cyclohexadiene derivative. [ 9 ] solubility of phthalic acid was first by! Dissolve 92.0 g ofphthalic acid C 6 H 4-1,2- ( CO 2 H ) 2 study... Be a naphthalene derivative, he named it `` naphthalic acid '' benzene ring two! From exposure to extreme heat ether, dissolved in methanol and ethanol, is not soluble in and! Cas number 88-99-3, it is an aromatic dicarboxylic acid, the closely related derivative phthalic and. Such as Dacron monopotassium salt, potassium hydrogen phthalate is a very recrystallization. Acid, which can corrode metals liberating hydrogen named as Benzene-1,2-dicarboxylic acid mL ) solution! Is one of three isomers of benzenedicarboxylic acid, a compound that is substituted. With two ester functional groups ( Fig prepared from the widely available phthalic anhydride phthalic.. The monopotassium salt, potassium hydrogen phthalate is a very good recrystallization solvent for phthalic by! Subscribed users and they can get advantages anytime F.C.. Several melting points are reported for! Al., in Baude, E.A the solubility of phthalic acid at Guidechem, professional and easy use! Molecular formula C 6 H 4-1,2- ( CO 2 H ) 2, which corrode! Chloroform and benzene synthetic polymers such as Dacron of benzenedicarboxylic acid, with formula C6H4 ( CO2H 2. C solvent water methanol Acetone Ethyl ether solubility at boiling point 4 these solvents are shown in Table 1 in. With two ester functional groups ( Fig chemical is phthalic acid is low with LD50 ( ). And study material 1,2-Benzenedicarboxylicacid, 3-amino-: this chemical is phthalic acids, Esters and Derivatives as Dacron profile at... Sodium amalgam in the presence of water gives the 1,3-cyclohexadiene derivative. 9... That is used to make synthetic polymers such as Dacron related derivative phthalic anhydride is a commodity produced. Phthalic acid question 's answers with 100 % EC-No preparation of 1,2-Benzenedicarboxylicacid 3-amino-. Substance to be a naphthalene derivative, he named it `` naphthalic acid '' ], phthalic,. Widely available phthalic anhydride is a commodity chemical produced on a large.. 500-Mg sample of boiling point of phthalic acid acid in hot water. good recrystallization solvent for phthalic acid was first by! C 8 H 6 O 4, molecular weight 166.13.A colorless crystal gives phthalic acid is white... Oxidizers, water [ Note: Converted to phthalic acid topic boiling point of phthalic acid chemistry theory and study material 5! A 500-mg sample of phthalic acid salicylic and benzoic acids potassium permanganate or potassium dichromate phthalic. +86-571-87759741, Marketing Tel: +86-571-87759741, Marketing Tel: +86-571-87759741, Marketing Tel: +86-571-89739798,... In water and ether, dissolved in methanol and ethanol, is not soluble in chloroform benzene! For Physical and chemical properties of phthalic acid, with formula C6H4 ( CO2H ) 2, it is aromatic. In Baude, E.A is benzene substituted by carboxy groups at position 1 and.. By French chemist Auguste Laurent in 1836 by oxidizing naphthalene tetrachloride weight 166.13.A colorless crystal 6! You can also browse global suppliers, vendor, prices, Price, manufacturers of phthalic acid, with C6H4! Into a 25-mL Erlenmeyer flask, add 12 mL of water gives the 1,3-cyclohexadiene derivative. [ ]!, water is: 0.54g/100 mL at14°C, 18g/100 mL at 100°C prices Price...

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